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Question

The incorrect option for free expansion of ideal gas under isothermal condition is

A
ΔH=0
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B
ΔS=0
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C
ΔT=0
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D
w=0
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Solution

The correct option is B ΔS=0
(i) In free expansion Pext=0 therefore w=0
(ii) For isothermal process
ΔH=nCPΔT=0
ΔU=nCVΔT=0
(iii) Entropy increases during the expansion

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