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Question

The increase of pressure on ice water system at constant temperature will lead to:

A
a decrease in the entropy of the sysytem
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B
an increase in the Gibbs energy of the system
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C
a shift of the equilibrium in the forward direction
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D
no effect on the equilibrium
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Solution

The correct option is C a shift of the equilibrium in the forward direction
The volume of liquid water at freezing temperature is lower than the volume of ice. When pressure is increased, more ice will melt to form liquid water. The increase of pressure on icewater system at constant temperature will lead to a shift of the equilibrium in the forward direction as the volume is less in the forward direction.
i.e. P 1V

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