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VSEPR Theory

The increasin...

Question

The increasing $d$ -character in hybridisation of $X e$ in $X e F_{2}, X e F_{4}, X e F_{6}$ is :

X e F_{2} < X e F_{4} < X e F_{6}

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X e F_{4} < X e F_{2} < X e F_{6}

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X e F_{6} < X e F_{4} < X e F_{2}

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X e F_{2} < X e F_{6} < X e F_{4}

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Solution

The correct option is A $X e F_{2} < X e F_{4} < X e F_{6}$
$X e F_{2} = 2 + \frac{8 - 2}{2}$
$= 2 + 3$ $s p^{3} d$
$X e F_{4} = 4 + \frac{8 - 4}{2}$
$= 4 + 2$ $s p^{3} d^{2}$
$X e F_{6} = 6 + \frac{8 - 6}{2}$
$= 6 + 1$ $s p^{3} d^{3}$
$∴$ increasing d character
$X e F_{6} > X e F_{4} > X e F_{2}$

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