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Question

The increasing order of basicity of the following compounds is:


A
(d)<(b)<(a)<(c)
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B
(a)<(b)<(c)<(d)
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C
(b)<(a)<(c)<(d)
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D
(b)<(a)<(d)<(c)
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Solution

The correct option is D (b)<(a)<(d)<(c)
Here, (c) is the most basic because its conjugate acid is stabilized by equivalent resonance. Out of (a) and (d), (d) is more basic due to +I effect. (b) is less basic than (a) and (d) because the N atom is sp2 hybridised.

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