The increasing order of reactivity of the substrates for $S_{N} 1$ reaction is

Benzyl chloride

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Tert - butylchloride

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Allyl chloride

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Ethylchloride

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Solution

Greater the stability of the carbocation, greater will be the reactivity of its substrate.

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(I) . C H_{3} C H (C l) C H_{2} C H_{3}

(I I) . C H_{3} C H_{2} C H_{2} C l

(I I I) . p - H_{3} C O - C_{6} H_{4} - C H_{2} C l

S_{N} 1

\begin{matrix} C H_{3} C H C H_{2} C H_{3} | C l & C H_{3} C H_{2} C H_{2} C l & p - H_{3} C O - C_{6} H_{4} - C H_{2} C l (I) & (I I) & (I I I) \end{matrix}

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