The initial concentration of cane sugar is presence of an acid was reduced from 0.20 to 0.1M in 5hours and to 0.05M in 10hours value of K ?
Ans .0.1368/hour pls put it on paper
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Solution
From unit of k in the option ,you can determine the order of reaction.Here hour^-1 >1st order reaction. Or else Assume reaction is 1st order reaction
case 1 At=Concentraion at time t A0=intial concentration t-time case 1: t1=5 At1=0.1 log[At1/A0] = -kt1 ln[A0/At1] = kt =>k=ln[0.2/0.1]/5 =0.1386/hour case 2 At2=0.05: t2=10 log[At2/A0] = -kt2 ln[A0/At2] = kt =>k=ln[0.2/0.05]/10 =0.1386/hour There ofr evalue of k is same for both reactions So the reaction is first order and value of k=0.1386/hour =>Our assumption was correct. If we assume reaction is any other order(0,2,..etc),value of k will be different for both cases.