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Question

The inner orbital complex which exhibits both geometrical as well as optical isomerism.

A
[Cr(en)3]3+
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B
[IrF3(H2O)2(NH3)]
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C
[NiCl2(en)2]
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D
[Co(CN)2(ox)2]3
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Solution

The correct options are
C [NiCl2(en)2]
D [Co(CN)2(ox)2]3
[Cr(en)3]3+;Hyb,:d2sp3; does not exhibit geometrical isomerism but exhibits optical isomerism.

[Irf3(H2O(NH3)];Hyb.:d2sp3; exhibits geometrical isomerism but does not exhibit optical isomerism.

[NiCl2(en)2];Hyd.:sp3d2; exhibits both geometrical isomerism and optical isomerism.

[Co(CN)3(ox)2]3;Hyb.:d2sp3; exhibits both geometrical isomerism and optical isomerism.

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