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Question

The intermediate compound formed when acetylene is hydrated in presence of dil. H2SO4 and HgSO4 is:

A
acetaldehyde
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B
ethanol
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C
vinyl chloride
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D
ethenal
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Solution

The correct option is B ethanol
In this reaction "ethenol" forms as intermediate.

HCCH+H2OH2SO4(dil.)−−−−−−HgSO4H2C=CHOHH3CCHO(on rearrangement)

Hence, the correct option is B

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