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Question

The internal energy change when a system goes from state A to B is 40 kJ/mol. If the system goes from A to B by a reversible path and returns to state A by an irreversible path. What would be the net change in internal energy?

A
40 kJ
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B
>40 kJ
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C
<40 kJ
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D
Zero
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Solution

The correct option is B Zero
Internal energy is a state function. It is not path-dependent.
ΔU=UfUi

Since the system returns to its initial state, Uf=Ui.

Hence, ΔU=0

Hence, option D is correct.

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