The internal energy of a diatomic gas us given as U=U0V, where U0 is a constant . Molar heat capacity of gas is
It is given that U=U0V
For a diatomic molecule, internal energy is given by
U=52nRT
U0V=52nRT
Taking derivative on both sides.
U0dVdT=52Rn
Cv=52R(∵U0dUndT=Cv)
Hence, molar heat capacity is [52R].