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Question

The inversion temperature Ti(K) of hydrogen is:


[Given: Van der Waal's constants a and b are 0.244 atm L2mol−2 and 0.027 L mol−1 respectively]

A
440
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B
220
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C
110
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D
330
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Solution

The correct option is B 220
Gases become cooler during Joule Thomson's expansion only if they are below a certain temperature known as inversion temperature (Ti).

The inversion temperature is characteristic of each gas and is given by Ti=2abR
where R is gas constant

Given:
a=0.244 atm L2mol2
b=0.027 L mol1
R=0.0821 L atm K1mol1

Ti=2×0.2440.027×0.0821=220 K

Hence, the correct answer is option B.

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