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Question

The ion CIF−2 is linear, but the ion CIF+2 is bent. Hybridization schemes for the central Cl atom to account for this difference in structure.

A
CIF2sp3d
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B
CIF+2sp3
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C
CIF+2sp3d
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D
CIF2sp3
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Solution

The correct options are
A CIF+2sp3
B CIF2sp3d
ClF2 is sp3d hybridized (three lone pairs of Cl at three corners and two F at vertices) and ClF+2 is sp3 (two lone pairs on Cl and 2 bond pairs with F) hybridized.

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