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Question

The ionic mobility of alkali metal ions in aqueous solution is maximum for:

A
K+
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B
Rb+
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C
Li+
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D
Na+
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Solution

The correct option is B Rb+
As smaller the size of cation greater will be hydration of the metal cation.
In case of K+,Rb+,Li+,Na+

As Rb+ has larger size than other cations, so it will be less hydrated compared to others. So less number of H2O molecule will cover the Rb+ cation and more ease will be for movement of Rb+ cation in solution as compared to other cations.

Hence, ionic mobility of alkali metal ions in aqueous solution is maximum for Rb+.

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