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Question

The ionic radii of K+,Na+,Al3+ and Mg2+ are in the order

A
Na+<K+<Mg2+<Al3+
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B
Al3+<Mg2+<K+<Na+
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C
Al3+<Mg2+<Na+<K+
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D
K+<Al3+<Mg2+<Na+
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Solution

The correct option is C Al3+<Mg2+<Na+<K+
Ionic radii (in pm)
Na+ 102
K+ 138
Mg2+ 72
Al3+ 53.5
Al, Mg and Na are in third period.
Generally among the ions of same period, higher the charge on cation smaller will be its ionic radius.
Potassium belongs to the fourth period and shall have highest radius than the rest.
Al3+<Mg2+<Na+<K+
Option (c) is the correct answer.

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