The ionisation isomer of $[C o (e n)_{2} C l (N O_{2})] S C N$ is/are

[C o (e n)_{2} C l (S C N)] N O_{2}

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[C o (e n)_{2} (O N O) C l] (S C N)

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[C o (e n)_{2} (N O_{2}) C l] (H_{2} O)

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None of the above

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Solution

The correct option is A $[C o (e n)_{2} C l (S C N)] N O_{2}$
In these isomers there is a exchange of ligands between coordination sphere and ionisation sphere. These isomers give different ions when dissolved in water.

Option (a) compound is formed by exchange of $N O_{2}$ group with $S C N$

Hence, compounds in option (a) is ionisation isomers of given complex compound.

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Similar questions

Q. The ionisation isomer of

[C r {(H_{2} O)}_{4} C l (N O_{2})] C l

is:

Due to the presence of ambidentate ligands coordination compounds show isomerism. Palladium complexes of the type $[P d (C_{6} H_{5})_{2} (S C N)_{2}]$ and $[P d (C_{6} H_{5})_{2} (N C S)_{2}]$ are
(a) linkage isomers
(b) coordination isomers
(c) ionisation isomers
(d) geometrical isomers

[C r (N H_{3})_{6}] [C r (S C N)_{6}]

and

[C r (N H_{3})_{2} (S C N)_{4}] [C r (N H_{3})_{4} (S C N)_{2}]

are the examples of what type of isomerism?

The d and l isomer of [Co(en)₃]³⁺are type of:

Q. Write the formula of ionisation isomer of

[C r (H_{2} O)_{4} B r_{2}] C l

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The ionisation isomer of [Co(en)2Cl(NO2)]SCN is/are

The ionisation isomer of $[C o (e n)_{2} C l (N O_{2})] S C N$ is/are