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Question

The ionisation isomer of [Cr(H2O)4Cl(NO2)]Cl is:

A
[Cr(H2O)4(O2N)]Cl2
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B
[Cr(H2O)4Cl2](NO2)
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C
[Cr(H2O)4Cl(ONO)]Cl
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D
[Cr(H2O)4Cl2(NO2)]H2O
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Solution

The correct option is B [Cr(H2O)4Cl2](NO2)
Ionisation isomers are complexes that produces different ions in solution, i.e., they have ions interchanged inside and outside the coordination sphere.
[Cr(H2O)4Cl(NO2)]Cl and [Cr(H2O)4Cl2]NO2 have different ions inside and outside the coordination sphere and hence are ionisation isomers.

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