The ionization energy of hydrogen atom is -13.6 eV. The energy required to excite the electron in a hydrogen atom from the ground state to the first excited state is: (Avogadro's constant =6.022 × 1023)
1.69 × 10-23 J
E=−13.6n2
E=−13.64=-3.4 eV
We know that energy required for excitation is △ E=E2−E1=-3.4-(-13.6)=10.2 eV
Therefore energy required for excitation of electron per atom =10.26.02×1023=1.69×10−23J