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Question

The ionization energy of hydrogen is 13.6eV. The first ionization energy of He is 24.6eV. Calculate the energy given out when He2+ nucleus combines with two electrons to form a helium atom in ground state.

A
68.2eV
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B
51.8eV
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C
38.2eV
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D
79eV
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Solution

The correct option is C 79eV
The first ionization energy of H to H+ is 13.6 eV.
The first ionization energy of He to He+ is 24.6 eV......(1)
When a He2+ ion accepts an electron, the energy released is Z2=22=4 times the first ionization energy of hydrogen atom.
Thus, the energy for the ionization of He2+ to He+ is 4×13.6=54.4eV......(2)
When (1) and (2) are added, we get the energy given out when He2+ ion gains 2 electrons and forms He atom in its ground state.
It will be 24.6eV+54.4eV=79eV.

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