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Question

The IUPAC name for the complex [Co(NO2)(NH3)5]Cl2 is:


A
pentaamminenitrito-N-cobalt(III) chloride
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B
nitrito-N-pentaamminecobalt(III) chloride
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C
pentaamminenitrito-N-cobalt(II) chloride
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D
pentaamminenitrito-N-cobalt(I) chloride
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Solution

The correct option is A pentaamminenitrito-N-cobalt(III) chloride
Oxidation number of Co is x1 = 2 x=3

Nitrogen is donating its lone pairs in the given compound.
The IUPAC name is pentaamminenitrito-N-cobalt(III) chloride.

Hence option A is correct.

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