The IUPAC name of the complex $[{(C O)}_{3} F e {(C O)}_{3} F e {(C O)}_{3}]$ is:

nonacarbonyldiiron (0)

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tricarbonyliron (0)-m-tricarbonyl iron (0)

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hexacarbonyliron (0)-m-tricarbonyl iron (0)

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tri-

μ

-carbonylbis(tricarbonyliron (0))

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Solution

The correct option is D tri- $μ$ -carbonylbis(tricarbonyliron (0))
The bridging ligands which link the two metal atoms together are indicated by the prefix $- μ -$ .

If there are two or more bridging groups of the same kind, this is indicated by di $- μ -$ , tri $- μ -$ etc.

As carbonyl is a neutral ligand oxidation number of metal $(F e)$ will be zero.

Hence, option D is correct.

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The IUPAC name of the complex [(CO)3Fe(CO)3Fe(CO)3] is:

The IUPAC name of the complex $[{(C O)}_{3} F e {(C O)}_{3} F e {(C O)}_{3}]$ is: