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Question

The IUPAC name of the following compound CH3−CH3|C|CH3−CH3 is .


A
2,2dimethylpropane
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B
1,1,1,1tetramethylmethane
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C
2methylbutane
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Solution

The correct option is A 2,2dimethylpropane
The carbon atom at the center has 4 methyl groups attached to it. If you carefully count the number of ways we can choose the longest chain, there would be 6 such ways.

Irrespective of the choice, the central carbon gets numbered '2'. Also there are 2 methyl groups attached to the central carbon atom.

∴ The primary suffix here is -ane, word root is 'prop' and prefix is 2,2-dimethyl. Hence, the IUPAC name is 2,2-dimethylpropane.

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