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Byju's Answer
Standard XII
Chemistry
Ostwald Dilution Law
The Ka of p...
Question
The
K
a
of propionic add is
1.34
×
10
−
5
. What is the
p
H
of a solution containing
0.5
M propionic acid and
0.5
M sodium propionate?
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Solution
As we know that,
p
K
a
=
−
log
K
a
∵
K
a
=
1.34
×
10
−
5
(
Given
)
∴
p
K
a
=
−
log
(
1.34
×
10
−
5
)
⇒
p
K
a
=
5
−
0.127
=
4.873
Now,
p
H
=
p
K
a
+
log
(
[
salt
]
[
acid
]
)
Given:-
[
salt
]
=
[
acid
]
=
0.5
M
∴
p
H
=
4.87
+
log
0.5
0.5
=
4.873
Hence the pH of the solution is
4.873
.
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0
Similar questions
Q.
What will be the new
p
H
if
0.01
m
o
l
of
H
C
l
is added to a
1
L
buffer solution that is
0.02
M
in propionic acid
(
C
H
3
C
H
2
C
O
O
H
)
and
0.015
M
in sodium propionate
(
C
H
3
C
H
2
C
O
O
N
a
)
?
Dissociation constant
K
a
of propionic acid at
25
∘
C
is
1.34
×
10
−
5
(Take
l
o
g
(
1.34
)
=
0.13
)
Q.
A buffer solution was prepared by dissoving
0.02
mol propionic acid and
0.015
mol sodium propionate in enough water to make
1.00
L
of solution.
(
K
a
for propoinic acid is
1.34
×
10
−
5
).
What is the
p
H
of the buffer?
Q.
A Student planned an experiment that would use
0.10
M
propionic acid,
C
H
3
C
H
2
C
O
O
H
. Calculate the value of
[
H
+
]
and the
p
H
for this solution. For propionic acid,
K
a
=
1.34
×
10
−
5
.
Q.
How many moles of sodium propionate
(
C
H
3
C
H
2
C
O
O
N
a
)
should be added to one litre of an aqueous solution containing 0.02 mole of propionic acid
(
C
H
3
C
H
2
C
O
O
H
)
to obtain a buffer solution of
p
H
=
5.87
?
Dissociation constant of propionic acid
K
a
at
25
∘
C
is
1.34
×
10
−
5
Take
l
o
g
(
1.34
)
=
0.13
Q.
How many moles of sodium propionate
(
C
H
3
C
H
2
C
O
O
N
a
)
should be added to one litre of an aqueous solution containing 0.02 mole of propionic acid
(
C
H
3
C
H
2
C
O
O
H
)
to obtain a buffer solution of
p
H
=
5.87
?
Dissociation constant of propionic acid
K
a
at
25
∘
C
is
1.34
×
10
−
5
Take
l
o
g
(
1.34
)
=
0.13
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