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Question

The Kα x-ray emission line of tungsten occurs at λ = 21 pm. What is the energy difference between EK and EL levels in this atom (MeV refers to mega electron volts;1MeV = 106 eV and hc = 1242 eVnm)?

A
0.59 MeV
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B
1.2 MeV
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C
59 KeV
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D
13.6 eV
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Solution

The correct option is A 0.59 MeV
Kα x-ray emission takes place when an electron jumps from L-shell to fill a vacancy created in K-shell.
Now EK is the energy of the atom when vacancy is in K-Shell, and EL Is the energy of the atom when vacancy is created in L-Shell. Also, EK > EL So, when vacancy shifts from K to L, according to our agrument, the atomic energy decreases. How much ?
EKEL.
This difference results into X-ray photon.
Hence connecting the dots we can conclude that ; The energy difference between K and L levels is the energy of the photon.
Mathematically;
EKEL=Ephoton

Now,
EKEL=hcλ

Which gives after putting in the values;
EKEL=1242 eVnm0.0021nm

Final calculations leads us to our answer;
EKEL=591428eV
Or,
EKEL=0.59MeV

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