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Byju's Answer
Standard XII
Chemistry
Reaction Quotient
The kinetic d...
Question
The kinetic datas for the reaction :
2
A
+
B
2
→
2
A
B
are as given below:
[
A
]
m
o
l
L
−
1
[
B
2
]
m
o
l
L
−
1
Rate
m
o
l
L
−
2
m
i
n
−
1
2
1.0
2.5
×
10
−
3
1.0
1.0
2.5
×
10
−
3
2
2.0
1
×
10
−
2
Hence the order of reaction w.r.t
A
and
B
2
are _____ respectively.
A
0
and
2
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B
2
and
1
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C
1
and
2
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D
2
and
2
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Solution
The correct option is
D
0
and
2
No Dependence on
[
A
]
→
ϑ
∝
[
A
]
0
Quadratic Dependence on
[
B
]
→
ϑ
∝
[
B
]
2
ϑ
=
k
[
A
]
0
[
B
]
2
=
k
[
B
]
2
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0
Similar questions
Q.
The kinetic datas for the reaction:
2
A
+
B
2
→
2
A
B
are as given below:
[
A
]
m
o
l
L
−
1
[
B
2
]
m
o
l
L
−
1
Rate mol
L
−
1
m
i
n
−
1
0.5
1.0
2.5
×
10
−
3
1.0
1.0
5.0
×
10
−
3
0.5
2.0
1
×
10
−
2
Hence the order of reaction with respect to A and
B
2
are, respectively:
Q.
The kinetic datas for the reaction :
2
A
+
B
2
→
2
A
B
arre as given below:
[
A
]
(
m
o
l
L
−
1
)
[
B
2
]
(
m
o
l
L
−
1
)
R
a
t
e
(
m
o
l
L
−
1
m
i
n
−
1
)
0.5
1.0
2.5
×
10
−
3
1.0
1.0
5.0
×
10
−
3
0.5
2.0
1
×
10
−
2
Hence the order of reaction with respect to
A
and
B
2
are respectively :
Q.
Following data are given for the reaction between
A
and
B
.
[
A
]
/
m
o
l
L
−
1
[
B
]
/
m
o
l
L
−
1
Initial rate/
m
o
l
L
−
1
s
−
1
at
300
K
320
K
2.5
×
10
−
4
3.0
×
10
−
5
5.0
×
10
−
4
2.0
×
10
−
3
5.0
×
10
−
4
6.0
×
10
−
5
4.0
×
10
−
3
-
1.0
×
10
−
3
6.0
×
10
−
5
1.6
×
10
−
2
-
The rate constant at
300
K
is:
Q.
For the reaction,
2
N
O
+
2
H
2
→
N
2
+
2
H
2
O
, the following kinetic data were obtained:
Expt.
No.
[
H
2
]
(
m
o
l
L
−
1
)
[
N
O
]
(
m
o
l
L
−
1
)
Rate of reaction
(
m
o
l
L
−
1
s
−
1
)
1.
0.12
0.12
0.25
×
10
−
4
2.
0.12
0.24
1.0
×
10
−
4
3.
0.24
0.24
2.0
×
10
−
4
Determine the rate law and the rate constant.
Q.
The experimental data for the reaction
2
A
+
B
2
⟶
2
A
B
, is:
Expt. No.
[
A
]
[
B
2
]
Rate
(
m
o
l
L
−
1
s
−
1
)
1.
0.50
0.50
1.6
×
10
−
4
2.
0.50
1.00
3.2
×
10
−
4
3.
1.0
1.00
3.2
×
10
−
4
The rate equation for the above data is:
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