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Question

The Ksp of BaCrO4 is 2.4×1010M2. The maximum concentration of Ba(NO3)2 possible without precipitation in a 6×104MK2CrO4 solution is ?

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Solution

Ba(NO3)2+KrCrO4BaCrO4+2KNO3
Ksp of BaCrO4=2.4×1010M2
=[Ba2+][CrO24]
Concentration of [CrO24] ions
=6×104M
We get CrO24 ions from KrCrO4
2.4×1010M2=[Ba2+][CrO24]2.4×1010M=[Ba2+][6×104][Ba2+]=2.47×10106×104=4×105M
Concentration of Ba2+ ions =4×105M.

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