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Question

The Lewis acid strength of BBr3,BCl3 and BF3 is in the order.

A
BBr3<BCl3<BF3
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B
BCl3<BF3<BBr3
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C
BF3<BCl3<BBr3
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D
BBr3<BF3<BCl3
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Solution

The correct option is D BF3<BCl3<BBr3
Order of back bonding
BF3>BCl3>BBr3
Back bonding 2p2p, 2p3p, 2p4p
Stronger is the back bonding weaker the tendency to act as a lewis acid
BF3<BCl3<BBr3

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