The liquids which do not dissolve in water are called
The liquids which do not dissolve in water are called immiscible liquids. E.g., petrol, diesel, mustard oil, etc.
Separating immiscible liquids is done simply using a separating funnel. The two liquids are put into the funnel and are left for a short time to settle out and form two layers. The tap of the funnel is opened and the bottom liquid is allowed to run. The two liquids are now separate.