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Synthesis of Esters from Acid Chlorides and Anhydrides

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Question

The major product (C) in the reaction is:

A

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B

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C

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D

All

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Solution

The correct option is C
Here, $2^{o} (- O H)$ group would be sterically more hindrered when ester with bulky (PhCO) group is formed. Hence, $1^{o} (- O H)$ group reacts.

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Synthesis of Esters from Acid Chlorides and Anhydrides

Standard XII Chemistry