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Question

The major product in the following reaction is Ph−Cl+Br2Anhydrous FeBr3−−−−−−−−−−−→ Product

A
o-bromochlorobenzene
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B
m-bromochlorobenzene
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C
2, 4, 6-tribromochloro benzene
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D
p-bromochlorobenzene
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Solution

The correct option is D p-bromochlorobenzene
Since, Cl group attached to benzene is ortho and para directing, so it forms o and pbromochlorobenzene products in electrophilic substitution reaction of chlorobenzene but the major product will be para product because ortho is disfavourd due to inductive effect and steric hindrance.

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