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Question

The major products A and B formed in the following reaction sequence are :


\( A \frac{ Br _{2^{2}} CH _{3} COOH }{\text { Room Temperature }} \rightarrow B \)

A
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B
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C
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D
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Solution

The correct option is D
Aniline reacts with acetic anhydride to form acetanilide which on further undergo aromatic electrophilic substitution reaction with Br2.
Amide is a ortho/para directing group.
Para product is major due to the steric hindrance at ortho position.

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