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Question

The mass of Al(OH)3 that was obtained by the reaction of 133.4 g of AlCl3 with 40 g of NaOH according to following equation is 13 g.
AlCl3+NaOHAl(OH)3+NaCl (not balanced)
Calculate the percentage yield.

(Molar mass of aluminium chloride is 133.34 g/mol, molar mass of NaOH is 40 g/mol and molar mass of aluminium hydroxde is 78 g/ mol respectively)

A
50
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B
100
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C
75
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D
65
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Solution

The correct option is A 50
The balanced equation is:
AlCl3+3NaOHAl(OH)3+3NaCl

Moles of aluminium chloride = 133.34133.34=1
Moles of NaOH = 4040=1

According to the balanced chemical equation, 1 mole of aluminium chloride requires 3 moles of NaOH . But the number of moles of NaOH available is 1. Hence, NaOH is the limiting reagent.
Hence, the moles of aluminium hydroxide formed = 0.33

Mass of aluminium hydroxide formed = 0.33×78 = 26 g

Theoretical yield = 26 g
Experimental yield = 13 g

Percentage yield = experimental yieldtheoretical yield×100=1326×100=50%

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