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Question

The mass of phosphoric acid required to obtain 53.4 g pyrophosphoric acid is :

A
58.8 g
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B
60.2 g
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C
65.8 g
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D
68.3 g
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Solution

The correct option is A 58.8 g
2H3PO4H4P2O7+H2O

One mole of pyrophosphoric acid will require two moles of phosphoric acid.

The molar masses of pyrophosphoric acid and phosphoric acid are 177.98 g/mol and 98 g/mol respectively.

177.98 gm of pyrophosphoric acid requires 2×98 gm phosphoric acid.

Therefore 53.4 gm requires 2×98×53.4177.98 gm of phosphoric acid.
=58.8 gm

Hence, option A is correct.

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