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Question

The maximum number of structural isomers of primary amine having the molecular formula C5H11NH2 is:

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Solution

Primary amine can be formed by replacing one H atom with NH2 group.

The number of structural isomers possible for pentane is 3, as shown below:

From (i), three primary amines are possible. From (ii), four amines are possible and from (iii), one amine is possible.
Hence, a total of eight structural isomers are possible as shown below:

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