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Byju's Answer
Standard XII
Chemistry
Bleaching Powder
The melting p...
Question
The melting point of
2
-nitrophenol is lower than that of
4
-nitrophenol and this is because of
A
intramolecular hydrogen bonding in
2
- nitrophenol
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B
intramolecular hydrogen bonding in
4
- nitrophenol
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C
intermolecular hydrogen bonding in
2
- nitrophenol
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D
hydrogen bonding has no relation to the melting point
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Solution
The correct option is
A
intramolecular hydrogen bonding in
2
- nitrophenol
Intramolecular hydrogen bonding.
So,o-nitro phenol has low melting point p-nitro phenol.
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Similar questions
Q.
Ortho-nitrophenol is steam volatile whereas para-nitrophenol is not. This is due to
1.
Intramolecular hydrogen bonding present in ortho-nitrophenol
2.
Intermolecular hydrogen bonding present in para-nitrophenol
3.
Intramolecular hydrogen bonding present in para-nitrophenol
4.
Inter-molecular hydrogen bonding present in ortho-nitrophenol.
Q.
Assertion :Boiling point of p-nitrophenol is greater than that of o-nitrophenol. Reason: There is intramolecular hydrogen bonding in p-nitrophenol and intermolecular hydrogen bonding in o-nitrophenol.
Q.
Given below are two statement:
Statement I: o-Nitrophenol is steam volatile due to intramolecular hydrogen bonding.
Statement II: o-Nitrophenol has high melting point due to hydrogen bonding.
Q.
The concept that explains why
o
−
nitrophenol is more volatile than
p
−
nitrophenol is
.
Q.
Assertion :Boiling and melting points of amides are higher than corresponding acids. Reason: It is due to strong intermolecular hydrogen bonding in their molecules.
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