The mixture that forms maximum boiling azeotrope is

Water + nitric acid

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Acetone + carbon disulphide

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Ethanol + water

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Heptane + octane

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Solution

The correct option is A Water + nitric acid
Maximum boiling azeotropes are formed by those solutions which show negative deviations from Raoult’s law. $H_{2} O$ and $H N O_{3}$ mixture shows negative deviations.

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Question 25
On the basis of information given below mark the correct option. Information On adding acetone to methanol some of the hydrogen bonds between methanol molecules break.
(a) At specific composition methanol-acetone mixture will form minimum boiling azeotrope and will show positive deviation from Raoult's law
(b) At specific composition methanol-acetone mixture will form maximum boiling azeotrope and will show positive deviation from Raoult's law
(c) At specific composition methanol-acetone mixture will form minimum boiling azeotrope and will show negative deviation from Raoult's law
(d) At specific composition methanol-acetone mixture will form maximum boiling azeotrope and will show negative deviation from Raoult's law

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The mixture that forms maximum boiling azeotrope is

The correct option is A Water + nitric acidMaximum boiling azeotropes are formed by those solutions which show negative deviations from Raoult’s law. H2O and HNO3 mixture shows negative deviations.

The correct option is A Water + nitric acid
Maximum boiling azeotropes are formed by those solutions which show negative deviations from Raoult’s law. $H_{2} O$ and $H N O_{3}$ mixture shows negative deviations.