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Question

The molar conductivity of 0.025 mol L−1 methanoic acid is

46.1 S cm2 mol−1.

Calculate its degree of dissociation and dissociation constant. Given λ °(H+)

= 349.6 S cm2 mol−1 and λ °(HCOO−) = 54.6 S cm2 mol

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Solution

C = 0.025 mol L−1

Now, degree of dissociation:

Thus, dissociation constant:


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