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Question

The molar enthalpy of vaporization of benzene at its boiling point (353K) is 29.7 KJ mol. For how long (minute) would a 11.4 Volt source need to supply a 0.5 A Current in order to vaporise 7.8 g of the, sample at its boiling point?

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Solution

Solution:-
Molecular weight of benzene =78g/mol
Weight of benzene =7.8g
No. of moles of benzene =7.878=0.1 mole
Given that energy provided to evaporate 1 mole of benzene =29.7kJ/mol
Energy provided to evaporate 0.1 mole of benzene (E)=29.97×0.1=2997J
As we know that,
E=V×I×t
Given that,
V=11.4 volt
t=?
I=0.5A
2997=11.4×0.5×t
t=29975.7=525.79s
Hence for t=525.79s, a 11.4 volt source need to supply a 0.5A current in order to vaporise 7.8g of the sample at its boiling point.

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