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Question

The molar heat capacity in a process of diatomic gas if it does a work of Q4 when a heat of Q is supplied to it is

A
25R
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B
54R
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C
103R
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D
64R
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Solution

The correct option is B 103R
First law of Thermodynamics we have :-

Q=w+ΔU (1)

where,

Q = Heat supplied to the gas

w = Work done by the gas

ΔU = Change in the internal energy of the gas

Given :-

w=Q/4 (2)

From (1) & (2) we have :-

ΔU=3Q/4 (3)

Now,

ΔU=nRΔTγ1 (4)

where,

n = No. of moles of gas

ΔT = Change in temperature

R = Universal Gas Constant

γ = Specific heat ratio

For a diatomic gas :-

γ=7/5 ( 5)

Using (3), (4) & (5) we get :-

nΔT=3Q10R (6)

Also note that :-

Q=nCΔT (7)

where,

C = Molar specific heat for the process

So now replace nΔT in (7) by (6) :-

3QC10R=Q

C=10R3

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