The correct option is D 103R
We know that,
dU=CvdT
For a diatomic gas Cv=52R
dU=52RdT
dT=25RdU ......(1)
Now, we have from the first law of thermodynamics,
dQ=dU+dW
dU=dQ−dW
Given that dQ=Q and dW=Q4
dU=Q−Q4=3Q4 ......(2)
So, we have the molar heat capacity as
C=dQdT
C=Q×5R2dU [From (1)]
C=Q×5R2×(3Q4) [From (2)]
⇒C=10R3