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Question

The molar heat capacity in a process where a diatomic gas does a work of Q/4 when a heat of Q is supplied to it is

A
53R
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B
73R
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C
83R
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D
103R
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Solution

The correct option is D 103R
We know that,

dU=CvdT

For a diatomic gas Cv=52R

dU=52RdT

dT=25RdU ......(1)

Now, we have from the first law of thermodynamics,

dQ=dU+dW

dU=dQdW

Given that dQ=Q and dW=Q4

dU=QQ4=3Q4 ......(2)

So, we have the molar heat capacity as

C=dQdT

C=Q×5R2dU [From (1)]

C=Q×5R2×(3Q4) [From (2)]

C=10R3

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