The molar ionic conductance at infinite dilution of Mg2+ and Cl− ions are 106.1 and 76.3S cm2 mol−1 respectively. The molar conductance of a solution of MgCl2 at infinite dilution is:
A
29.8S cm2 mol−1
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B
183.4S cm2 mol−1
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C
285.7S cm2 mol−1
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D
258.7S cm2 mol−1
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Solution
The correct option is D258.7S cm2 mol−1 Λ0(MgCl2)=λ0Mg2++2λ0Cl− =106.1+2×76.3 =258.7S cm2 mol−1