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Question

The mole fraction of CH3OH in an aqueous solution is 0.02 and its density is 0.994gcm3. Determine its molarity and molality.

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Solution

Let x mole of CH3OH and y mole of water be present in solution.
Mole fraction of CH3OH=xx+y=0.02
So,
yx=49 or xy=149

Molality =x18×y×1000=100018×49=1.13m

Volume of solution =Total massdensity=32x+18y0.994mL

=32x+18y0.994×1000litre=32x+18y994litre

Molarity =x32x+18y×994

=99432+18×y/x=99432+18×49=1.0875M

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