The correct option is B 3
Positional isomers are constitutional isomers that have the same carbon skeleton and the same functional groups but differ from each other in the location of the functional groups on or in the carbon chain. C5H12O is formula of Pentanol. It may have 3 positional isomers.
1−pentanol,CH3−CH2−CH2−CH2−CH2−OH
2−pentanol,CH3−CH2−CH2−CH−(OH)−CH3
3−pentanol,CH3−CH2−CH(OH)−CH2−CH3