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Question

The molecular shapes of diborane is shown below.
Consider the following statements for diborane :
1. Boron is approximately sp3 hybridised
2. BHB angle is 180
3. There are two terminal BH bonds for each boron atom
4. There are only 12 bonding electrons available

The correct statements are:


A
1, 3 and 4 are correct
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B
1, 2 and 3 are correct
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C
2, 3 and 4 are correct
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D
1,2 and 4 are correct
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Solution

The correct option is A 1, 3 and 4 are correct
Boron has 4 hybridised orbitals, out of which 3 orbitals are occupied with one electron each and rest one is an empty orbital.
BHB bond angle is less than 180
There are two terminal B-H bonds for each boron atom.
There are only 12 valence electrons, 3 in each B atom and 1 in each H atom. Thus there are only 12 bonding electrons available.

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