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Question

The molecule that has the change in heat capacity at higher temperatures among the following is

A
CH4
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B
CO2
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C
H2O
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D
All of the above
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Solution

The correct option is D All of the above
Normally at room temperature, vibrational energy will not contribute to the heat capacity. But at higher temperature vibrational energy contribute to the total heat capacity. and hence heat capacities changes at higher temperature.
CH4,CO2,H2O all the three molecules have vibrational contribution to the total energy at higher temperature.

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