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Question

The molecule which contains sp3d2 and p orbitals overlapping in it is:

A
PCl5
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B
BrF5
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C
ClF3
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D
IF7
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Solution

The correct option is B BrF5
The molecular geometry of BrF5 is octahedral based on its electron pair geometry . The hybridization is sp3d2 wherein one s, three p and two d orbitals of bromine hybridize to form sp3d2 hybrid orbitals. These form a bond with p orbital of fluorine atoms.
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