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Question

The molecules of the alkene family are represented by a general formula CnH2n. Answer the following:
(i) What do n and 2n signify?
(ii) What is the name of alkene when n = 4?
(iii) What is the molecular formula of the alkene, if there are six hydrogen atoms in it?
(iv) Write the molecular and structural formula of the first member of alkene family.
(v) Write the molecular formulae of lower and higher homologues of an alkene which contains four carbon atoms.

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Solution

(i) The molecules of the alkene family are represented by a general formula CnH2n where n and 2n signify the number of carbon and hydrogen atoms, respectively.

(ii) When n = 4, the alkene is butene (C4H2(4) = C4H8).

(iii) In an alkene, the number of carbon atoms is always half the number of hydrogen atoms present. So, if there are 6 hydrogen atoms in the alkene then there must be 3 carbon atoms present. Hence, the molecular formula of alkene will be C3H6.

(iv)The first member of the alkene family is ethene.
Molecular formula is: C​2H4
The structural formula is:


(v)The alkene which contains four carbon atoms is butene (C4H8). There is always a difference of CH2 between two successive members of a homologous series. Hence, the lower and higher structural homologues of butene (C4H8) are propene (C​3H6) and pentene (C5H10), respectively.

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