The most basic amine among the following is:

p - t o l u i d i n e

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o - n i t r o a n i l i n e

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p - n i t r o a n i l i n e

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2, 4 - d i n i t r o a n i l i n e

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Solution

The correct option is A $p - t o l u i d i n e$
The most basic amine among the following is $p - t o l u i d i n e$ as all the other compounds contain an extra nitro group where as p-toluidine contains only an extra alkyl group contributing to a normal carbon chained compound

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p K_{b}

C_{2} H_{5} N H_{2}, C_{6} H_{5} N H C H_{3}, (C_{2} H_{5})_{2} N H

C_{6} H_{5} N H_{2}

C_{6} H_{5} N H_{2}, C_{6} H_{5} N (C H_{3})_{2}, (C_{2} H_{5})_{2} N H

C H_{3} N H_{2}

p-Nitroaniline is obtained by

- N H_{2}

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