The most important commercial process of ammonia synthesis is:
The Haber process, also called the Haber–Bosch process, is
an artificial nitrogen fixation process and is the main industrial procedure
for the production of ammonia today. It is named after its inventors, the
German chemists Fritz Haber and Carl Bosch, who developed it in the first half
of the 20th century. The process converts atmospheric nitrogen (N2) to ammonia (NH3) by a reaction with hydrogen (H2) using a metal catalyst under high
temperatures and pressures. The reaction is given below.
N2+3H2⟶2NH3 (ΔH°=−91.8kJ)or(ΔH°=−45.8kJ⋅mol−1)