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Question

The most ionic and most covalent compounds respectively from the following are:
CrO5, Mn2O7, PbO, P4O10, SnO2

A
CrO5,Mn2O7
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B
PbO,Mn2O7
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C
CrO5,P4O10
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D
SnO2,CrO5
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Solution

The correct option is B PbO,Mn2O7
As anion is same, the covalent character in ionic compound will depend upon the size and charge on the cation. According to Fajan's rule, PbO is most ionic because Pb2+ has less polarising power where as Mn2O7 is most covalent because Mn7+ has higher polarising power.
Hence, the most ionic compound is PbO and most covalent is Mn2O7.

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