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Question

The most suitable reagent for the following conversion is:


A

KMnO4

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B

K2Cr2O7

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C

CrO3

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D

PCC (pyridinium chlorochromate)

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Solution

The correct option is D

PCC (pyridinium chlorochromate)


The other three all contain aqueous media (we should not have moisture/water). PCC helps stop at the aldehyde stage whereas the other three all convert the alcohol directly into acid. Isolation at aldehyde is not feasible. PCC gives the aldehyde.


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